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4 edition of The Anomeric effect and associated stereoelectronic effects found in the catalog.

The Anomeric effect and associated stereoelectronic effects

The Anomeric effect and associated stereoelectronic effects

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  • 13 Currently reading

Published by American Chemical Society in Washington, DC .
Written in English

    Subjects:
  • Isomerism.,
  • Stereochemistry.

  • Edition Notes

    StatementGregory R.J. Thatcher, editor.
    SeriesACS symposium series ;, 539
    ContributionsThatcher, Gregory Robert James, 1959-, American Chemical Society. Division of Carbohydrate Chemistry., American Chemical Society. Meeting
    Classifications
    LC ClassificationsQD471 .A56 1993
    The Physical Object
    Paginationxi, 305 p. :
    Number of Pages305
    ID Numbers
    Open LibraryOL1423908M
    ISBN 100841227292
    LC Control Number93034423

    Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and reactivity of organic molecules. This advanced textbook provides an up-to-date overview of the field, starting from the fundamental principles and presenting a large selection of modern examples of stereoelectronic effects in organic reactivity. Nasrin Masnabadi, Afshin Taghva Manesh and Fatemeh Azarakhshi, Ab Initio Calculations of the Conformational Preferences of 1,3-OxathianeS-Oxide and its Analogs ContainingSandSEAtoms—Evidence for Stereoelectronic Interactions Associated with the Anomeric Effects, Phosphorus, Sulfur, and Silicon and the Related Elements, , 8, (), ().Cited by:

    Definition: Stereoelectronic effects – interactions of electronic orbitals in three dimensions. The typical stereoelectronic effect involves an electronic interaction which stabilizes a particular conformation or transition state and is fully expressed only when the correct geometry is achieved. Caveat: “stereoelectronic” is not the same File Size: 8MB. Anomeric effect Last updated Janu The α- and β-anomers of D-glucopyranose.. In organic chemistry, the anomeric effect or Edward-Lemieux effect is a stereoelectronic effect that describes the tendency of heteroatomic substituents adjacent to a heteroatom within a cyclohexane ring to prefer the axial orientation instead of the less hindered equatorial orientation that would be.

      The anomeric effect is a chemical phenomenon 1,2,3,4,5,6,7,8,9 that refers to an observed stabilization 10 of six-membered carbohydrate rings when they contain an . β‐Silicon effect and related β‐effects n/σ‐Interactions Anomeric effects Reverse anomeric effect “Anomeric effects without lone pairs”: beyond the n → σ* interactions n/π‐Interactions Esters and related carboxylic acid derivatives File Size: 1MB.


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The Anomeric effect and associated stereoelectronic effects Download PDF EPUB FB2

Anomeric effect: how it came to be postulated / John T. Edward --Anomeric and associated stereoelectronic effects: scope and controversy / Gregory R.J. Thatcher --Intramolecular strategies and stereoelectronic effects: glycosides and orthoesters hydrolysis revisited / P. Deslongchamps --Anomeric and gauche effects: some basic.

The Anomeric Effect and Related Stereoelectronic Effects at Oxygen. Authors: Kirby, A. Free PreviewBrand: Springer-Verlag Berlin Heidelberg. The anomeric effect and associated Stereoelectronic effects The anomeric effect and associated Stereoelectronic effects Tvaroska, Igor CARBOHYDRATE RESEARCH ELSEVIER Carbohydrate Research () C9-C10 Book review The Anomeric Effect and Associated Stereoelectronic Effects, ACS Symposium SeriesEdited by Gregory R.J.

Thatcher. Equally important, however, are three additional chapters that deal with the general consequences of the stereoelectronic interactions that are associated with the basis of the anomeric effect.

The remainder of the book is devoted to new areas of development in the The Anomeric effect and associated stereoelectronic effects book as differentiation of the endo and exo anomeric interactions.

Stereoelectronic Effects. Welcome,you are looking at books for reading, the Stereoelectronic Effects, you will able to read or download in Pdf or ePub books and notice some of author may have lock the live reading for some of ore it need a FREE signup process to obtain the book.

If it available for your country it will shown as book reader and user fully subscribe will benefit by. : The Anomeric Effect and Related Stereoelectronic Effects at Oxygen (Reactivity and Structure: Concepts in Organic Chemistry) (): Anthony John Kirby, Dennis Young: BooksCited by: 2 THE ANOMERIC EFFECT AND ASSOCIATED STEREOELECTRONIC EFFECTS Barton's ideas found immediate application in Professor Cocker's researches[6,7].

Furthermore, with J.C.P. (Peter) Schwarz, the other lecturer in Organic Chemistry at. Get this from a library. The anomeric effect and associated stereoelectronic effects: developed from a symposium sponsored by the Division of Carbohydrate Chemistry at the th National Meeting of the American Chemical Society, Washington, DC, August[Gregory Robert James Thatcher; American Chemical Society.

Division of Carbohydrate Chemistry. Anomeric and Reverse Anomeric Effect in Acetals and Related Functions F. Grein Chap DOI: /bkch Publication Date (Print): Novem The Anomeric effect and associated stereoelectronic effects / Author: Gregory R.J. Thatcher, editor. Publication info: Washington, DC: American Chemical Society, The book has countless examples of stereoelectronic effects from the literature, but unfortunately, it never really introduces the theory behind it in a systematic way.

It essentially goes through examples of stereoelectronic effects, based on functional group, starting with the acetal. This book should be useful to researchers but not by: Machine derived contents note: Anomeric Effect: How It Came To Be Postulated, J.T. Edward; Anomeric and Associated Stereoelectronic Effects: Scope and Controversy, G.R.J.

Thatcher; Intramolecular Strategies and Stereoelectronic Effects: Glycosides and Orthoesters Hydrolysis Revisited, P. relative to endo anomeric effect view here H O CH3 O H O Anomeric Effect=(exo-AEeq)-(exo-AEax+endo-AEax) Praly, J.

P., Lemieux, R.U., Can. Chem.65, endo anomeric effect is absent in the equitorial conform so this term is zero BuSn Effect is observed in dioxanes and dithianes: O O S S X X simple extention of the tetrahydropyran File Size: 1MB.

This chapter also introduces a number of classic stereoelectronic effects on reactivity such as the gauche effect, the anomeric and homoanomeric effects, the β-silicon and β-tin effects etc.

The Anomeric Effect and Related Stereoelectronic Effects at Oxygen. Authors (view affiliations) Anthony John Kirby Search within book. Front Matter. Pages i-viii. PDF. Anthony John Kirby. Pages Stereoelectronic Effects on Reactivity: The Kinetic Anomeric Effect. Anthony John Kirby.

Pages Appendix. Anthony John Kirby. Grein F () Anomeric and reverse anomeric effect in acetals and related functions. In: Thatcher GRJ (ed) The anomeric effect and associated stereoelectronic effects, ACS symposium series No. ACS, Washington, DC, pp – CrossRef Google ScholarAuthor: Momcilo Miljkovic.

Stereoelectronic interaction effects (associated with the anomeric effects) on the stability of the stereoisomers of 1,4,5,8-tetraoxadecalin, 1,4,5,8-tetrathiadecalin and 1,4,5,8-tetraselenadecalin.

An ab initio study and NBO analysis The most dominant conformation-controlling factor in carbohydrate compounds is known as anomeric effect (AE).Cited by: 7. The nature of the anomeric effect in the bicyclic trans-fused octahydromethyl-1H-2,1-benzothiazine 2,2-dioxide 37 has been examined by single crystal X-ray structure analysis (Figure 5).The crystal structure of 37 shows that the N-Me group assumes an axial position in the solid authors suggest that this conformation is also the most stable in solution and propose.

The Anomeric Effect and Related Stereoelectronic Effects at Oxygen Reactivity and Structure: Concepts in Organic Chemistry: : Anthony John Kirby, Dennis Young: Libros en idiomas extranjerosFormat: Tapa blanda.

For the design of organometallic catalytic reactions, one can apply stereoelectronic effects that are specific to the metal centers, such as the trans-effect. The anomeric effect provides multiple Author: Igor Alabugin.

The Anomeric Effect And Associated Stereoelectronic Effects. 49,9 Mb. Description: Discusses contemporary experimental and computational studies on the anomeric effect and related stereoelectronic effects and presents conflicting data and theories in this highly controversial area.

Explores applications in carbohydrate chemistry, including.Illustrated Glossary of Organic Chemistry Anomeric effect: Originally defined as the tendency of heteroatomic substituents (such as an OH group) adjacent to a heteroatom within a cyclohexane ring to prefer the axial orientation instead of the less hindered equatorial orientation that would be expected from steric considerations alone.

Stereoelectronic Effects in Action The Many Doors Opened by Orbital Interactions. Igor V. Alabugin. Department of Chemistry and Biochemistry, Florida State University, USA.